The five-day fashion extravaganza will start here March 12.
The actor is excited about it and all praise for the designer's menswear collection which is inspired by blue pottery.
"This is the first time I will walk the ramp so I am very excited," Ali said here during the press conference of the fashion week.
"I think I have never worn such beautiful clothes and for this the credit goes to designer Kunal Anil Tanna. He has used blue pottery in his collection, especially in menswear. Blue pottery is very famous in Jaipur. That's genius work of art," he added.
A total of 98 designers will participate at the LFW summer-resort 2014. Actress Mandira Bedi will also make her ramp debut as a designer and will showcase her new sari line.
Meanwhile, on being asked what he finds easier - acting or walking the ramp, Ali said: "Acting is more easy than walking the ramp. I am really amazed to see the people who walked the ramp here".
LFW will be opened by celebrity fashion designer Manish Malhotra.