The actor is hoping to wow the audience with his presence on the runway, and a source close to him said that he is "extremely excited" to be a showstopper for the latest collection by Rathore.
Meanwhile, Ali has been busy with the shooting of his next film, Mahesh Bhatt's "Khamoshiyan", but he took time out to fulfil his commitment for the show.
Actress Aditi Rao Hydari will also join him on the ramp.
For the show, to be held at DLF Emporio Friday, Rathore has created a line, which "celebrates the spiritual manifestation of a melange of traditions, ushering in a new era of clothes embodying history, a rebellion of colours splashing modernism on to the austere canvas of the ramp and where jewellery becomes the new tattoo for men".