Brad Pitt reportedly hated his wife Jennifer Aniston's chain-smoking habit and spoke of Angelina Jolie as a "goddess", model April Florio said.

Florio, who claimed that she had spent three days with the "Ocean's Twelve" star, said that he had tried to kiss her but she "shied away", reported Ananova quoting the magazine US Weekly.

Pitt also reportedly poured his heart out to Florio about his deteriorating marriage to the "Friends" star, she said.

"He hated his wife's chain-smoking. He also hated the fact that she liked to hang with her friends or just stay at home. He liked to go to parties more," she said.

And, asked about Jolie, the "Tomb Raider" actress, Florio said: "He talked about her like she was a goddess".

"He was attracted to me," the 22-year-old said.

But when Pitt made advances, Florio claims, "he was shocked (at her brush off). He asked me why. I told him I did not want to get involved with someone in the industry."